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A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst† †Electronic supplementary information (ESI) available. CCDC 1579606 (MUV-2). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04829
| Content Provider | Semantic Scholar |
|---|---|
| Author | Souto, Manuel Santiago-Portillo, Andrea Palomino, Miguel Vitórica-Yrezábal, Iñigo J. Vieira, Bruno J. C. Waerenborgh, João Carlos Valencia, Susana Navalón, Sergio Rey, Fernando García, Hermenegildo Espallargas, Guillermo Mínguez |
| Copyright Year | 2018 |
| Abstract | Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes. |
| Starting Page | 2413 |
| Ending Page | 2418 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 29732116v1 |
| Alternate Webpage(s) | https://doi.org/10.1039/c7sc04829g |
| DOI | 10.1039/c7sc04829g |
| Journal | Chemical science |
| Volume Number | 9 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Digital Object Identifier Electronic Supplementary Materials Organic solvent product oxidation tetrathiafulvalene |
| Content Type | Text |
| Resource Type | Article |
