NDLI: selective , and durable photocatalytic system for CO 2 reduction to formic acid †

Content Provider	Semantic Scholar
Author	Tamaki, Yusuke Koikec, Kazuhide Ishitani, Osamu
Copyright Year	2015
Abstract	We discovered an extremely suitable sacrificial electron donor, 1,3-dimethyl-2-(o-hydroxyphenyl)-2,3dihydro-1H-benzo[d]imidazole, for the selective photocatalytic reduction of CO2 to formic acid using a Ru(II)–Ru(II) supramolecular photocatalyst. The efficiency, durability, and rate of photocatalysis are significantly increased (FHCOOH 1⁄4 0.46, TONHCOOH 1⁄4 2766, TOFHCOOH 1⁄4 44.9 min ) in comparison with those using 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole or 1-benzyl-1,4dihydronicotinamide.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/22/f4/SC-006-C5SC02018B.PMC5947534.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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