Cyclisierung von Bis(2,2,2-trifluorethoxy)-1,2-diiminoethan mit Schwefel-, Selen-, Phosphor- und Arsenchloriden / Cyclisation of Bis(2,2,2-trifluoroethoxy)-1,2-diiminoethane with Sulfur, Selenium, Phosphorus, and Arsenic Chlorides

Content Provider	Semantic Scholar
Author	Roesky, Herbert W. Hofmann, Hartmut M.
Copyright Year	1984
Abstract	By the reaction of cyanogen with 2,2,2-trifluoroethanol in the presence of a base catalyst, bis(2,2,2-trifluoroethoxy)-1,2-diiminoethane (1) is obtained. 1 can be easily cyclized with halides to yield five-membered ring compounds. Triethylamine serves as an HCl-acceptor. The building elements of the rings are S 2, 3, Se 4, P 5 and As 6, respectively. 5 reacts with Mg to form the diphosphane 7.
Starting Page	1315
Ending Page	1318
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1515/znb-1984-1004
Volume Number	39
Alternate Webpage(s)	http://zfn.mpdl.mpg.de/data/Reihe_B/39/ZNB-1984-39b-1315.pdf
Alternate Webpage(s)	https://doi.org/10.1515/znb-1984-1004
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article