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Conversion of methanol into light olefins over ZSM-5 zeolite: Strategy to enhance propene selectivity
| Content Provider | Semantic Scholar |
|---|---|
| Author | Bleken, Francesca Lønstad Chavan, Sachin M. Olsbye, Unni Boltz, Marilyne Ocampo, Fabien Louis, Benoît |
| Copyright Year | 2012 |
| Abstract | Abstract Four ZSM-5 zeolite materials with varying crystal size, acid site density and morphology were prepared, characterized by BET, XRD, SEM, FT-IR, H/D exchange and n-hexane cracking experiments and tested as catalysts for the Methanol to Olefins (MTO) reaction at 350 °C, WHSV = 1.8 g/gh under atmospheric pressure. Optimal propene to ethene ratios (>5) were obtained over a material prepared via the fluoride route. Its superior selectivity was tentatively ascribed to its low density of strong acid sites in combination with a long diffusion pathway and few crystal defects. |
| Starting Page | 178 |
| Ending Page | 185 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.apcata.2012.09.025 |
| Volume Number | 447 |
| Alternate Webpage(s) | https://www.tpbin.com/download-firstpage/05472/article |
| Alternate Webpage(s) | https://doi.org/10.1016/j.apcata.2012.09.025 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |