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Unsymmetrical β-diketiminate magnesium(I) complexes: syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sheng, Xingchao Hua, Haiming Yao, Weiwei Pullarkat, Sumod A. Ma, Mengtao |
| Copyright Year | 2018 |
| Abstract | A series of unsymmetrical β-diketimine coordinated magnesium(I) complexes have been successfully synthesized via reductions of related magnesium(II) halide complexes with a sodium reducing reagent in toluene or n-hexane solution. All the unsymmetrical magnesium(I) complexes prepared have been crystallographically and spectroscopically characterized. It was found, for the first time, that these well-defined unsymmetrical magnesium(I) complexes were highly active pre-catalysts for the hydroboration of alkynes, nitriles, aldehydes and ketones. |
| Starting Page | 3538 |
| Ending Page | 3547 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C8QO00720A |
| Volume Number | 5 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c8/qo/c8qo00720a/c8qo00720a1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C8QO00720A |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |