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Nonanthocyanin secondary metabolites of black raspberry (Rubus occidentalis L.) fruits: identification by HPLC-DAD, NMR, HPLC-ESI-MS, and ESI-MS/MS analyses.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Paudel, Liladhar Wyzgoski, Faith J. Scheerens, Joseph C. Chanon, Ann M. Reese, Raylene Smiljanic, Danijela Wesdemiotis, Chrys Blakeslee, Joshua J. Riedl, Kenneth M. Rinaldi, Peter L. |
| Copyright Year | 2013 |
| Abstract | Nonanthocyanin secondary metabolites potentially contributing to the antiproliferative bioactivity of black raspberry ( Rubus occidentalis L.) fruits were extracted in ethyl acetate and isolated by semipreparative and analytical HPLC and analyzed by NMR, HPLC-ESI-MS, and ESI-MS/MS techniques. Here we present complete and partial structures of a variety of the chemical entities such as quercetin 3-glucoside, quercetin 3-rutinoside, myricetin glucoside, dihydrokaempferol glucoside, benzoic acid β-d-glucopyranosyl ester, 3,4-dihydroxybenzoic acid, epicatechin, caffeic acid, p-coumaric acid, p-coumaryl glucoside, p-coumaryl sugar ester, ellagic acid, methyl ellagic acid acetylpentose, methyl ellagic acid valerylpentose, trans-piceid, phloretin glucoside (phloridzin), dihydrosinapic acid, salicylic acid β-d-glucopyranosyl ester, a salicylic acid derivative without attached sugar, p-alkylphenyl glucoside, and a citric acid derivative. To our knowledge, 15 of these compounds were not previously reported in black raspberry fruits. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/jf4039953 |
| PubMed reference number | 24279806 |
| Journal | Medline |
| Volume Number | 61 |
| Issue Number | 49 |
| Alternate Webpage(s) | https://docs.wixstatic.com/ugd/a2fd64_75c3b3aacf1846b39361628cc3d8fe59.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/jf4039953 |
| Journal | Journal of agricultural and food chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |