NDLI: Enantioselective formal synthesis of (-)-englerin A via a Rh-catalyzed [4 + 3] cycloaddition reaction.

Content Provider	Semantic Scholar
Author	Xu, Jing Caro-Diaz, Eduardo J. E. Theodorakis, Emmanuel A.
Copyright Year	2010
Abstract	An enantioselective formal synthesis of (-)-englerin A (1) is reported. Key to the strategy is a Rh-catalyzed [4 + 3] cycloaddition reaction between furan 10 and diazo ester 11 that, following an intramolecular aldol condensation, produces the tricyclic scaffold of englerin. This strategy also provides a rapid, efficient, and stereoselective access to the biologically significant core motif of the guaiane sesquiterpenes.
File Format	PDF HTM / HTML
DOI	10.1021/ol1015652
PubMed reference number	20669919
Journal	Medline
Volume Number	12
Issue Number	16
Alternate Webpage(s)	http://theodorakisgroup.ucsd.edu/publications%20folder/2005-present/ET101SI(2).pdf
Alternate Webpage(s)	http://theodorakisgroup.ucsd.edu/publications%20folder/2005-present/ET101.pdf
Alternate Webpage(s)	http://doc.sciencenet.cn/upload/file/2012117161953566.pdf
Alternate Webpage(s)	https://doi.org/10.1021/ol1015652
Journal	Organic letters
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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