NDLI: Metal-Free Synthesis of Dibenzoxazepinones via a One-Pot SNAr and Smiles Rearrangement Process: Orthogonality with Copper-Catalyzed Cyclizations

Content Provider	Semantic Scholar
Author	Hurst, Terry Kitching, Matthew O. Frota, Lívia C. R. M. Da Guimarães, Keller Guilherme Dalziel, Michael E. Snieckus, Victor Dr.
Copyright Year	2015
Abstract	Reported is the transition-metal-free synthesis of substituted dibenzoxazepinones using a convergent domino SNAr–Smiles rearrangement–SNAr process. Substrate-scope investigations demonstrated the critical importance of ring electronic effects on the efficiency of the process. In addition, the orthogonality of this approach with transition-metal-catalyzed procedures was established.
Starting Page	1455
Ending Page	1460
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1055/s-0034-1378839
Volume Number	26
Alternate Webpage(s)	https://www.thieme-connect.de/media/synlett/201511/supmat/sup_st-2015-b0267-l_10-1055_s-0034-1378839.pdf
Alternate Webpage(s)	https://doi.org/10.1055/s-0034-1378839
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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