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Vapor − liquid equilibrium measurements of the binary mixtures CO 2 + acetone and CO 2 + pentanones
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hsieh, Chieh-Ming Vrabec, Jadran |
| Copyright Year | 2015 |
| Abstract | Vapor−liquid equilibrium (VLE) data of the binary mixtures carbon dioxide (CO2) + acetone and CO2 + pentanones (i.e. all C5-ketones, which are 3-methyl-2-butanone, 2-pentanone, and 3-pentanone) are measured at 313.15 K, 333.15 K, and 353.15 K up to a pressure of 11.8 MPa using a high pressure view cell technique based on the synthetic method. The VLE measurement results of CO2 + acetone are compared to the available experimental data from the literature in order to validate the employed experimental apparatus. In case of binary CO2 + pentanone mixtures, only for CO2 + 3-methyl-2-butanone and CO2 + 2-pentanone at 313.15 K experimental data are available in the literature. The present measurements thus complete the literature database for binary VLE of CO2 + pentanones. All present data are compared to the results from the Peng−Robinson equation of state (PR EOS) with the van der Waals one-fluid mixing rule and from the combination of the PR EOS with the UNIQUAC model through the Huron−Vidal mixing rule. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://mb.uni-paderborn.de/fileadmin/thet/Publikationen/Veroeffentlichungen/CO2_Ketones-2.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |