NDLI: Lewis adduct formation of hydrogen cyanide and nitriles with arsenic and antimony pentafluoride.

Content Provider	Semantic Scholar
Author	Saal, Thomas Christe, Karl O. Haiges, Ralf
Copyright Year	2018
Abstract	The reactions of hydrogen cyanide, butyronitrile, cyclopropanecarbonitrile, pivalonitrile and benzonitrile with arsenic pentafluoride and antimony pentafluoride result in the formation of 1 : 1 Lewis adducts, while malononitrile yielded both 1 : 1 and 1 : 2 Lewis adducts. All adducts were isolated and characterized by multinuclear NMR and vibrational spectroscopy, and in most cases by their X-ray crystal structures.
Starting Page	99
Ending Page	106
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1039/c8dt03970d
PubMed reference number	30457603
Journal	Medline
Volume Number	48
Issue Number	1
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/dt/c8dt03970d/c8dt03970d1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c8dt03970d
Journal	Dalton transactions
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Lewis adduct formation of hydrogen cyanide and nitriles with arsenic and antimony pentafluoride.