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Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?
| Content Provider | Semantic Scholar |
|---|---|
| Author | Tong, King-Lung Yee, Chi-Chung Au-Yeung, Ho Yu |
| Copyright Year | 2016 |
| Abstract | We report here a DCL study of a phenanthroline-based building block focusing on catenane formation with copper templates. Two [2]catenanes have been amplified by using Cu+ as a template from the DCLs that contain no interlocked compounds in the absence of copper. In addition, an unexpected Cu2+ template effect on the [2]catenane formation was discovered. The observed Cu2+ template effect was found to originate from the in situ reduction of the divalent metal to Cu+. |
| Starting Page | 348 |
| Ending Page | 353 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5QI00227C |
| Volume Number | 3 |
| Alternate Webpage(s) | http://hub.hku.hk/bitstream/10722/226306/1/Content.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5QI00227C |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |