NDLI: Transmission of Substituent Effects through Five-Membered Heteroaromatic Rings. III. Addition Equilibria of Hydroxide Anion to Benzaldehyde Analogues

Content Provider	Semantic Scholar
Author	Sohn, Chang Kook Chun, Young Il Rhee, Soon Ki Kim, Chang Kon Kim, Chan Kyung Lee, Ikchoon
Copyright Year	2000
Abstract	ρZ > 0, indicating that the substituent (Z) effects are not transmitted by a direct conjugation. The magnitude of ρZ for Y=NH is the largest among the heteroaromatic systems, which is consistent with the largest transmission efficiency change (ΔS). The equilibria for the addition processes are favorable in the gas phase ( ΔG o 0) due to the relatively large solvation energy of OH - in the initial state in aqueous solution. The orders of ΔG o and ρZ in the gas phase are almost maintained in solution.
Starting Page	1202
Ending Page	1206
Page Count	5
File Format	PDF HTM / HTML
Volume Number	21
Alternate Webpage(s)	http://ocean.kisti.re.kr/downfile/volume/chemical/JCGMCS/2000/v21n12/JCGMCS_2000_v21n12_1202.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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