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Synthesis and characteristics of iron nanoparticles in a carbon matrix along with the catalytic graphitization of amorphous carbon
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sajitha, E. P. Prasad, Vishwanath Subramanyam, Sudha Eto, Soichiro Takai, Kazuyuki Enoki, Toshiaki |
| Copyright Year | 2004 |
| Abstract | Iron nanoparticles in a carbon matrix were synthesized by in situpyrolysis of maleic anhydride and ferrocene, using different molecular weight percentages. The characterization and magnetic properties of the carbon-iron system were investigated systematically. Transmission electron microscope (TEM) images showed that the as-prepared samples consist of nanometric dark grains (iron-rich phase) embedded in a light matrix (carbon-rich phase). X-ray diffraction and TEM selected area diffraction revealed catalytic graphitization and iron phases presentin the sample. The carbon-metal system shows a finite hysteresis loop even at room temperature indicating its ferromagnetic nature. The saturation magnetization equals the bulk iron carbide value at low temperature. The coercive force exhibits 1/d dependence at low temperature having a maximum H-C of 2 kOe for the lowest iron concentration sample. |
| Starting Page | 2815 |
| Ending Page | 2820 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.carbon.2004.06.027 |
| Volume Number | 42 |
| Alternate Webpage(s) | http://eprints.iisc.ac.in/2827/1/A29nanopart.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/j.carbon.2004.06.027 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |