Bis(benzyltriphenylphosphonium) bis(1,2‐dicyanoethene‐1,2‐dithiolato)nickel(II)

Content Provider	Semantic Scholar
Author	Zhou, Jia-Rong Ni, Chun-Lin Yu, Lin-Liang
Copyright Year	2007
Abstract	The asymmetric unit of the title compound, (C25H22P)2-[Ni(C4N2S2)2] or (BzTPP)2[Ni(mnt)2] (where BzTPP is 1-benzyl­triphenyl­phosphonium and mnt is maleonitrile­dithiol­ate), consists of one (BzTPP)+ cation and one-half of a centrosymmetric [Ni(mnt)2]2− anion. The NiII atom of the anion is coordinated by four S atoms from two mnt2− ligands and exhibits the expected square-planar coordination geometry. The (BzTPP)+ cation adopts a conformation where the four phenyl rings are twisted with respect to the plane of the P—C—C chain that links them. Weak C—H⋯N and C—H⋯π inter­actions are present in the crystal structure.
File Format	PDF HTM / HTML
DOI	10.1107/S1600536807018715
Volume Number	63
Alternate Webpage(s)	http://journals.iucr.org/e/issues/2007/05/00/kj2051/kj2051.pdf
Alternate Webpage(s)	https://doi.org/10.1107/S1600536807018715
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article