NDLI: Syntheses , Structures and Redox Properties of New Macrocyclic Triazatriolefinic Pd 0 Complexes and Their Polypyrrole Modified Electrodes Application to Heterogeneous Catalytic Suzuki Cross-Coupling Reactions

Content Provider	Semantic Scholar
Author	Llobet, Antoni Masllorens, Ester Rodríguez, Montserrat Belart Roglans, Anna Benet-Buchholz, Jordi
Copyright Year	2004
Abstract	New triolefinic macrocyclic ligands of the type (E,E,E)-1,6,11tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene (aryl: a = ferrocenyl, b = 4-pyrrol-1-ylphenyl, c = 4-methylphenyl) and their Pd0 complexes (1aab, 1abb and 1bcc) have been prepared and characterized. Further structural characterization in the solid state has also been performed by means of X-ray diffraction analysis for the complex 1bcc. The redox properties of both the ligands and their Pd complexes have been studied using cyclic voltammetric and coulombimetric techniques. In particular, complexes and ligands containing the pyrrole group do polymerize upon exposure to
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://tnt.udg.edu/gr_metso/material/(2004EJIC1601).pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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