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Synthesis of 4′-Functionalized 2,2′:6′,2′′-Terpyridines via the Pyridone Route: Symmetric and Asymmetric Bis-Complex Formation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Andres, Pr Philip Hofmeier, H. Harald Lohmeijer, Bgg Bas Schubert, Ulrich S. |
| Copyright Year | 2003 |
| Abstract | 2,2':6',2"-Terpyridines functionalized in the 4'-position have been prepared by reaction of 2,6-bis-(pyrid-2-yl)-4-pyridone under basic conditions with different electrophiles. The electrophiles consist of functionalized alkyl chains, which are terminated with different anionic leaving groups such as bromides, chlorides and tosylates. These reactions yielded terpyridines, which were modified at the 4'-position with heptoxy-, bromodecanoxy-, cyanopropoxy-, allyloxy-, styrene-4-ethoxy-, as well as (methoxy-ethoxy)-ethoxy functionalities. In an approach towards new functional materials based on polymerizable bis-terpyridyl metal-ion complexes, the 4'-epoxy-methoxy terpyridine was complexed with Co(II) in order to yield the paramagnetic bis-complex, which still could be characterized via 1 H NMR spectrometry. Additionally, in order to obtain an asymmetric bis-complex with two different terpyridine ligands, methyl-diethyleneoxy-terpyridine-Ru(II)-terpyridine-oxyheptane was prepared utilizing a directed coupling method via Ru(III)/Ru(II) chemistry. |
| Starting Page | 2865 |
| Ending Page | 2871 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1055/s-2003-42443 |
| Volume Number | 2003 |
| Alternate Webpage(s) | http://www.xiuzhengrd.com/ejournals/pdf/synthesis/doi/10.1055/s-2003-42443.pdf |
| Alternate Webpage(s) | https://doi.org/10.1055/s-2003-42443 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
