NDLI: Rhodium-catalyzed pyridannulation of indoles with diazoenals: a direct approach to pyrido[1,2-a]indoles.

Content Provider	Semantic Scholar
Author	Dawande, Sudam Ganpat Lad, Bapurao Sudam Prajapati, Sunitkumar Sreenivas Katukojvala
Copyright Year	2016
Abstract	A novel rhodium catalyzed pyridannulation of 3-substituted indoles with diazoenals furnished privileged pyrido[1,2-a]indoles. The reaction is proposed to involve a [4 + 2]-annulation of the diacceptor rhodium enalcarbenoid via C-2 functionalization of the indole. The utility of the methodology was demonstrated with a short synthesis of the tetrahydropyrido[1,2-a]indole core, present in a large number of biologically important polycyclic indole alkaloids.
Starting Page	29
Ending Page	31
Page Count	3
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://www.indiana.edu/~chemdev/ishc/wp-content/uploads/2016/10/2016-5-September.pdf
Alternate Webpage(s)	http://www.rsc.org/suppdata/c6/ob/c6ob00360e/c6ob00360e1.pdf
PubMed reference number	26964882v1
Alternate Webpage(s)	https://doi.org/10.1039/c6ob00360e
DOI	10.1039/c6ob00360e
Journal	Organic & biomolecular chemistry
Volume Number	14
Issue Number	24
Language	English
Access Restriction	Open
Subject Keyword	Indole Alkaloids Indoles Rhodium Secologanin Tryptamine Alkaloids
Content Type	Text
Resource Type	Article

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