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Interface-directed assembly of a simple precursor of [FeFe]–H2ase mimics on CdSe QDs for photosynthetic hydrogen evolution in water
| Content Provider | Semantic Scholar |
|---|---|
| Author | Li, Cheng-Bo Li, Zhijun Yu, Shan Wang, Ge‐ Xia Wang, Feng Meng, Qing-Yuan Chen, Bin Feng, Ke Ke Tung, Chen-Ho Wu, Lizhu |
| Copyright Year | 2013 |
| Abstract | To prepare a water-soluble catalyst for photocatalytic hydrogen (H2) evolution, a simple hydrophobic precursor of [FeFe]–H2ase mimics, Fe2S2(CO)6, has been successfully assembled on the surface of CdSe QDs using an interface-directed approach in aqueous/organic solution. The resulting photocatalyst shows the highest efficiency known to date for H2 evolution with a turnover number (TON) of 8781 vs. Fe2S2(CO)6 and an initial turnover frequency (TOF) of 596 h−1 under visible light irradiation in water. |
| Starting Page | 2597 |
| Ending Page | 2602 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C3EE40992A |
| Volume Number | 6 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ee/c3/c3ee40992a/c3ee40992a.pdf |
| Alternate Webpage(s) | https://frontis-energy.com/wp-content/uploads/2018/05/hydrogenase/H2-Photocatalyst%20mimics%20FeFe-H2ase_LiEES2013.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C3EE40992A |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |