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Poly[[aqua[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2 N:N′](μ-isophthalato-κ2 O 1:O 3)copper(II)]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Gandolfo, Chaun M. Laduca, Robert |
| Copyright Year | 2010 |
| Abstract | In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is bis-(3-pyridylmeth-yl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by inter-layer O-H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement. |
| Starting Page | m318 |
| Ending Page | m318 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S160053681000632X |
| PubMed reference number | 21580257 |
| Journal | Medline |
| Volume Number | 66 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/9f/30/e-66-0m318.PMC2983567.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S160053681000632X |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |