NDLI: Efficient Mechanochemical Synthesis of Polyoxometalate⊂ZIF Complexes as Reusable Catalysts for Highly Selective Oxidation.

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Efficient Mechanochemical Synthesis of Polyoxometalate⊂ZIF Complexes as Reusable Catalysts for Highly Selective Oxidation.

Content Provider	Semantic Scholar
Author	Zhao, Xiaoxiao Duan, Yunpeng Yang, Fei Xu, Yanqing Hu, Changwen
Copyright Year	2017
Abstract	One-pot mechanochemical synthesis was demonstrated to be an efficient strategy to synthesize host-guest POM⊂rho-ZIF complexes (POM = polyoxometalate; rho-ZIF = zeolitic imidazolate framework with rho topology) with high crystallinity. In this work, the metastable rho-ZIF with large interior cavities and windows was used as host matrix for encapsulating and immobilizing bulky guest molecules with high loading efficiency and chemical stability. As novel catalysts, POM⊂rho-ZIF complexes were found effective for the selective oxidation of a series of sulfides to sulfoxides. Moreover, the heterogeneity of these composite catalysts was confirmed by leaching tests, and they can be recycled at least four times without significant loss of activity.
Starting Page	14506
Ending Page	14512
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1021/acs.inorgchem.7b02163
PubMed reference number	29144129
Journal	Medline
Volume Number	56
Issue Number	23
Alternate Webpage(s)	https://www.labxing.com/files/lab_publications/643-1538984247-746s1yGT.pdf
Alternate Webpage(s)	https://doi.org/10.1021/acs.inorgchem.7b02163
Journal	Inorganic chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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