NDLI: Copper-catalyzed enantioselective Mukaiyama aldol reaction of silyl enol ethers with isatins.

Content Provider	Semantic Scholar
Author	Li, Jindong Li, Yan-An Sun, Jianan Gui, Yang Huang, Yekai Zha, Zhenggen Wang, Zhiyong
Copyright Year	2019
Abstract	A highly enantioselective Mukaiyama aldol reaction of silyl enol ethers with isatins catalyzed by chiral copper complexes was developed. A series of chiral 3-substituted 3-hydroxy-2-oxindoles bearing a tetra-substituted center could be obtained exclusively with high yields (up to 95%) and excellent enantioselectivities (up to 99%). In particular, water was essential to improve the diastereoselectivity.
Starting Page	6309
Ending Page	6312
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/c9cc02159k
PubMed reference number	31089588
Journal	Medline
Volume Number	55
Issue Number	44
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/cc/c9cc02159k/c9cc02159k1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c9cc02159k
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Copper-catalyzed enantioselective Mukaiyama aldol reaction of silyl enol ethers with isatins.