Loading...
Please wait, while we are loading the content...
Similar Documents
Intramolecular hydrogen-bond-directed coordination: trans-bis(N-benzoyl-N'-propylthiourea-kappaS)diiodoplatinum(II) and trans-bis(N-benzoyl-N'-propylthiourea-kappaS)dibromoplatinum(II).
| Content Provider | Semantic Scholar |
|---|---|
| Author | Westra, Arjan N. Esterhuysen, Catharine Koch, Klaus R. |
| Copyright Year | 2004 |
| Abstract | In the title compounds, trans-[PtI2(C11H14N2OS)2], (I), and trans-[PtBr2(C11H14N2OS)2], (II), respectively, intramolecular NÐH O (propylamine side) hydrogen bonds in the potentially bidentate thiourea ligands lock the carbonyl O atoms into six-membered rings, determining the S-monodentate mode of coordination of these ligands. Intramolecular NÐH X (X is I or Br) interactions (benzoylamine side) lead to slight distortions of the Pt coordination spheres from ideal square-planar geometry. The Pt ion is located on an inversion centre in both structures. |
| File Format | PDF HTM / HTML |
| PubMed reference number | 15295172 |
| Journal | Medline |
| Volume Number | 60 |
| Part | 8 |
| Alternate Webpage(s) | https://journals.iucr.org/c/issues/2004/08/00/jz1636/jz1636.pdf |
| Journal | Acta crystallographica. Section C, Crystal structure communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |