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Crystal Structure Determination of a (μ-Amido)(μ-hydroxo)(μ-superoxo)dicobalt(III) Complex from the Werner Collection
| Content Provider | Semantic Scholar |
|---|---|
| Author | Spingler, Bernhard Scanavy-Grigorieff, Marie Werner, Alfred Berke, Heinz Lippard, Stephen J. |
| Copyright Year | 2001 |
| Abstract | By use of crystals from the Werner collection at the University of Zurich, the X-ray structure of a (μ-amido)(μ-hydroxo)(μ-superoxo)dicobalt(III) salt, probably synthesized around 1909, was determined. This complex is apparently the first dimetallic species with three bridging ligands of such a composition. The O−O bond distance of 1.340(4) A is consistent with a coordinated superoxo anion, and the two cobalt atoms are 2.776(1) A apart. |
| Starting Page | 1065 |
| Ending Page | 1066 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ic001137t |
| Alternate Webpage(s) | http://www.zora.uzh.ch/65629/1/Spingler_ic_submitted.pdf |
| Alternate Webpage(s) | http://www.columbia.edu/cu/chemistry/groups/gibney/Paper7.pdf |
| Alternate Webpage(s) | http://chem251.web.unc.edu/files/2016/03/InorgChem_2001_40_1065.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ic001137t |
| Volume Number | 40 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |