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μ‐Sulfato‐1κO:2κO‐μ‐oxo‐bis[tris(2‐pyridylmethyl)amine‐κ4N,N′,N′′,N′′′]diiron(III) diperchlorate acetonitrile/water (0.75/0.25) solvate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Smith, Christine M. Norman, Richard E. |
| Copyright Year | 2007 |
| Abstract | The title complex, [Fe2(C18H18N4)2O(SO4)](ClO4)2·0.75C2H3N·0.25H2O, consists of two perchlorate ions, a solvent cavity with acetonitrile and water (disordered 3/1), and an Fe complex dication. The dication is a diiron(III) unit containing an oxo bridge and a sulfato bridge. The iron(III) centers are pseudo-octahedral, six-coordinate, with tris(2-pyridylmethyl) amine (TPA) providing four N atoms. The distances and angles are typical for bent μ-oxo-bridged TPA complexes. The complex was the unexpected result of a reaction designed to produce a μ-sulfido–μ-carboxylato–diiron center. |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536807042857 |
| Volume Number | 63 |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2007/10/00/is2197/is2197.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536807042857 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |