NDLI: Synthesis and reactivity of novel organo main group and rare earth metal complexes

Content Provider	Semantic Scholar
Author	Zhu, Jing Chuan
Copyright Year	2014
Abstract	An ambiphilic bis(oxazolinyl)borane proligand and zinc dialkyls react via alkyl group transfer or β-hydrogen abstraction. Both alkyl abstraction and β-hydrogen abstraction processes can be observed, and products vary with coordinating solvent or noncoordinating solvent. We interpret this by proposing that the latter process is favoured by formation of a bis(oxazolinyl)borane-zinc adduct that positions a β-hydrogen in the proximity of the Lewis acid center.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://works.bepress.com/jiaxiangchu/17/download/
Alternate Webpage(s)	https://lib.dr.iastate.edu/cgi/viewcontent.cgi?article=4911&context=etd&httpsredir=1&referer=
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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