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Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Iwamoto, Hiroaki Kubota, Koji Yamamoto, Eiji Ito, Hajime |
| Copyright Year | 2015 |
| Abstract | The selective boryl substitution of alkyl halides bearing terminal C[double bond, length as m-dash]C double bonds has been achieved using a copper(i)/tricyclohexylphosphine or copper(i)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C[double bond, length as m-dash]C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes. |
| File Format | PDF HTM / HTML |
| PubMed reference number | 25977952 |
| Journal | Medline |
| Volume Number | 51 |
| Issue Number | 47 |
| Alternate Webpage(s) | https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/61453/1/boryl%20substitution_HUSCAP.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c5cc02760h |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |