Loading...
Please wait, while we are loading the content...
Similar Documents
Solvent induced photophysics and photochemistry of the (2p3s) Rydberg state of diazabicyclooctane : intersystem crossing, electron transfer, and energy transfer
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shang, Quan Yuan Moreno, P. O. Bernstein, Elliot R. |
| Copyright Year | 1994 |
| Abstract | Solvent induced singlet (2p3s) RydBerg state relaxation dynamics of diazabicyclooctane (DABCO) are studied in van der Waals clusters generated in a supersonic jet expansion. The excited-state decay is determined by a pump (excitation)/probe (ionization) mass selective technique. Solvents employed for these cluster studies include rare gases, saturated hydrocarbons and fluorocarbons, amines, ethers, methyl sulfide, acetonitrile, and aromatics. The nature of the intermediate states to which the nascent singlet (2p3s) Rydberg state decays is determined based on excited-state lifetimes, cluster dissociation products, and ionization energies |
| Starting Page | 311 |
| Ending Page | 319 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ja00080a036 |
| Volume Number | 116 |
| Alternate Webpage(s) | http://sites.chem.colostate.edu/bernsteinlab/144.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ja00080a036 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
