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Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Jin, Liqun Melaimi, Mohand Bertrand, Guy |
| Copyright Year | 2014 |
| Abstract | A cyclic C-bromo-iminium bromide reacts with lithium trimethylsilyl acetylide to afford the title compound 2+˙ in 40% yield. In contrast to other organic mixed valence compounds, this radical cation can be stored in air. Oxidation and reduction of 2+˙ afford the corresponding dication 2++ and neutral cumulene 2, respectively, in good yields. |
| Starting Page | 351 |
| Ending Page | 354 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4QO00072B |
| Volume Number | 1 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/qo/c4/c4qo00072b/c4qo00072b4.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C4QO00072B |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |