NDLI: Effect of alcohols on elution chromatography of trivalent actinides and lanthanides using tertiary pyridine resin with hydrochloric acid-alcohol mixed solvents.

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Effect of alcohols on elution chromatography of trivalent actinides and lanthanides using tertiary pyridine resin with hydrochloric acid-alcohol mixed solvents.

Content Provider	Semantic Scholar
Author	Ikeda, Atsushi Suzuki, Tatsuya Aida, Masao Fujii, Yasuhiko Itoh, Keisuke Mitsugashira, Toshiaki Hara, Mitsuo Ozawa, Masaki
Copyright Year	2004
Abstract	Elution chromatography with a tertiary pyridine resin has been used to separate the trivalent actinides (An3+) from the lanthanides (Ln3+) using an alcoholic hydrochloric acid solvent. Trivalent Am and Cm were separated from the Ln by employing a 1 cm(phi) x 10 cm resin column with the mixed solvent system composed of concentrated hydrochloric acid (HCl) and alcohols. The distribution coefficients (Kd) and the separation factors between An and Ln (alpha(An)(Ln)) increased as the alcohol content of the solvent mixture increased. On the other hand, the Kd and alpha(An)(Ln) decreased drastically upon the addition of water to the solvent mixture. Among the four alcohols investigated (methanol, ethanol, n-propanol and n-butanol), the ethanol-HCl mixed solvent system showed the largest Kd and alpha(An)(Ln). The mechanism of adsorption for An and Ln cations on the pyridine resin is discussed in addition to the results presented herein.
Starting Page	195
Ending Page	200
Page Count	6
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://www.review.imr.tohoku.ac.jp/papers/wos00-04/2004PDF/2004-31.pdf
PubMed reference number	15281269v1
Volume Number	1041
Issue Number	1-2
Journal	Journal of chromatography. A
Language	English
Access Restriction	Open
Subject Keyword	1-Butanol 1-Propanol Actinoid Series Elements Alcoholics Alcohols Cardiomyopathies Cations Concentrate Dosage Form Ethanol Hydrochloric Acid Lanthanoid Series Elements Methanol Pyridines Resin Cements Resins, Plant Solvents Thioctic Acid late nucleophagy tertiary trivalent influenza vaccine
Content Type	Text
Resource Type	Article

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