NDLI: Application of ruthenium complexes of triazole-containing tridentate ligands to asymmetric transfer hydrogenation of ketones.

Content Provider	Semantic Scholar
Author	Johnson, Tarn C. Totty, William G. Wills, Martin
Copyright Year	2012
Abstract	The synthesis of a series of tridentate ligands based on a homochiral 1,2-diamine structure attached to a triazole group and their subsequent applications to the asymmetric transfer hydrogenation of ketones are described. In the best cases, alcohols of up to 93% ee were obtained. Although base is not required, the use of Ru(3)(CO)(12) as metal source is essential, indicating a unique mechanism for the formation of the active catalyst.
File Format	PDF HTM / HTML
DOI	10.1021/ol302354z
PubMed reference number	23025546
Journal	Medline
Volume Number	14
Issue Number	20
Alternate Webpage(s)	http://wrap.warwick.ac.uk/55213/1/WRAP_9574780-ch-280915-ol-2012-02354z_redrafted_revision_251012%20(3).pdf
Alternate Webpage(s)	https://doi.org/10.1021/ol302354z
Journal	Organic letters
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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