Loading...
Please wait, while we are loading the content...
Similar Documents
Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wang, Xijia Zhang, Jian-Han Song, Jun-Ling Kong, Fang Mao, Jiang-Gao |
| Copyright Year | 2013 |
| Abstract | A series of new alkali metal and alkali-earth metal phosphites, namely, NaIn3(HPO3)5(H2O)4, AIn(HPO3)2 (A = Rb, Cs) and Ba3M2(HPO3)6 (M = Al, Ga, In), have been synthesized by hydrothermal reactions. Their structures have been determined by single-crystal X-ray diffraction. The structure of NaIn3(HPO3)5(H2O)4 shows a complicated 3D anionic framework based on InO6 octahedra connected by HPO3 tetrahedra via corner-sharing, and the 3D anionic network of NaIn3(HPO3)5(H2O)4 can also be described as a new 3,5-net with a Schlafli symbol of {4.82}{42.6.87}{42.6}3{42.88}{43.62.85}{83}. Both AIn(HPO3)2 (A = Rb, Cs) feature a 2D layer composed by InO6 octahedral and HPO3 tetrahedral units with alkali metal cations filling the interlayer spaces. Ba3M2(HPO3)6 (M = Al, Ga, In) are isomorphous, and their structures feature a 3D anionic framework composed of MO6 (M = Al, Ga, In) octahedra and HPO3 tetrahedra interconnected via corner-sharing. IR and UV-vis spectra and TGA curves of these materials were also measured. |
| Starting Page | 2519 |
| Ending Page | 2526 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C3CE26885C |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ce/c3/c3ce26885c/c3ce26885c.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C3CE26885C |
| Volume Number | 15 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
