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New insights into the reaction of zinc alkyls with dioxygen.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lewiński, Janusz Marciniak, Wojciech Lipkowski, Janusz Justyniak, Iwona |
| Copyright Year | 2003 |
| Abstract | Studies on the reaction of zinc alkyls with O2 are reported which demonstrate that the selective oxygenation of organozinc compound is viable. The reaction of [EtZn(azol)]n (azol = deprotonated 1-aziridineethanol) with an excess of dry O2 in toluene affords the zinc ethylperoxide [EtOOZn(azol)]2[EtZn(azol)]2, while the analogous reaction between Me2Zn and O2 results in the isolation of the Me6Zn7(OMe)8 cluster in high yield. |
| Starting Page | 28 |
| Ending Page | 31 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://lewin.ch.pw.edu.pl/wp-content/uploads/papers/ja2003_wm.pdf |
| PubMed reference number | 14558804v1 |
| Volume Number | 125 |
| Issue Number | 42 |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Azol Cell Respiration Dioxygen Toluene zinc pyrithione 10 MG/ML Medicated Shampoo |
| Content Type | Text |
| Resource Type | Article |