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Illustrating Catalysis with Interlocking Building Blocks: A BINAP–Ruthenium Complex Catalyzed Asymmetric Hydrogenation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Horikoshi, Ryo |
| Copyright Year | 2015 |
| Abstract | A unique method has been developed using an interlocking building-block model equipped with magnets to illustrate the catalytic asymmetric hydrogenation of β-keto esters by a BINAP–ruthenium complex to enhance students’ understanding of this process. A BINAP–ruthenium block model, mimicking the coordination environment around the metal center in the real complex, can be used to convert the β-keto ester model into a β-hydroxy ester model. This model was used to provide a greater understanding of the essence of the catalytic reaction and to assist students in their understanding of its mechanism. |
| Starting Page | 332 |
| Ending Page | 335 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ed500484u |
| Volume Number | 92 |
| Alternate Webpage(s) | http://pendidikankimia.walisongo.ac.id/wp-content/uploads/2018/10/21-1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ed500484u |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
