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Cavity enhanced absorption spectroscopy using room temperature quantum cascade lasers
| Content Provider | Semantic Scholar |
|---|---|
| Author | Welzel, Stefan Davies, Paul B. Engeln, Rah Richard Röpcke, Jürgen |
| Copyright Year | 2009 |
| Abstract | Achieving the high sensitivity necessary for trace gas detection generally requires long absorption path lengths. An alternative approach to conventional linear absorption spectroscopy employing multiple pass cells is to use a high finesse cavity. With the help of such cavities the effective path length of the laser beam in the absorbing medium can essentially be increased to more than the 200 m limit usually available from conventional optical multi-pass cells while keeping the sample and pumped volume small. Optical cavity based techniques, Cavity Ring Down Spectroscopy (CRDS) and Cavity Enhanced Absorption Spectroscopy (CEAS) among them, have been successfully applied as a highly sensitive absorption technique for several years. The majority of cavity based methods have used sources of radiation in the ultraviolet and visible regions. For many years the midinfrared (MIR) molecular fingerprint region could not be employed either for CRDS or for the CEAS techniques, because of the lack of suitable radiation sources with the required power and tunability and small scale dimensions. Experiments were carried out with optical parametric oscillators, Raman cells or shifters or CO and CO2 lasers. In all these cases sophisticated optical geometries were developed which were more suitable for the research laboratory than for field applications. Attempts to use lead salt lasers clearly suffered from low laser intensity. In addition, for wider application, especially for field measurements, compact and cryogen free spectrometers are definitely preferable. Recent advances in semiconductor laser technology, in particular the advent of quantum cascade lasers (QCL) provides new possibilities for highly sensitive and selective trace gas detection using MIR absorption spectroscopy. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://meetingorganizer.copernicus.org/EGU2009/EGU2009-12890.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |