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A Study on the Performance and Operation Limit of Electrodialysis Cell for HI Concentration
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lee, Byung-Woo Jeong, Seong-Uk Cho, Won-Chul Kang, Kyoung-Soo Park, Chu-Sik Bae, Ki-Kwang Kim, Young-Ho Kim, Chang-Hee |
| Copyright Year | 2011 |
| Abstract | The present work explores the performance and operation limit of electrodialysis cell for HI concentration in sulfur iodine thermochemical hydrogen production process, For this purpose, the electrodialysis cell was assembled with Nafion 117 as a PEM membrane and two activated carbon papers as the electrodes. HIx solution was prepared with composition of HI: I2: H2O = 1: 0.5~2.5: 5.2 in molar ratio. The cell and its peripheral apparatus were placed in the specially designed convective oven in order to uniformly maintain the operation temperature. As operation temperature increased, the amount of water transport from anode to cathode increased, thus reducing HI molarity in catholyte. Meanwhile, the current efficiency was constant as about 90 %, irrespective of temperature change. The cell voltage increased with initial I2 mole ratio as well as anolyte to catholyte mole ratio. Moreover the cell voltage overshot took place within 10 h cell operation, which is due to the I2 precipitation inside the cell. From the analysis of I2 mole ratio in the anolyte, it is noted that operation limit (in I2 mole ratio) of the electrodialysis cell, arising from was measured to be 3.2, which is much lower than bulk solubility limit of 4.7. |
| Starting Page | 749 |
| Ending Page | 758 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.7316/khnes.2011.22.6.749 |
| Volume Number | 22 |
| Alternate Webpage(s) | http://ocean.kisti.re.kr/downfile/volume/khnes/SSONB2/2011/v22n6/SSONB2_2011_v22n6_749.pdf |
| Alternate Webpage(s) | https://doi.org/10.7316/khnes.2011.22.6.749 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |