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Reversible-deactivation radical polymerization mediated by CuSO4·5H2O: an alternative and promising copper(II)-based catalyst
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhao, Junfei Wang, Wenxiang Bai, Liangjiu Zhou, Lili Cheng, Zhenping Zhang, Zhengbiao Zhu, Xiulin |
| Copyright Year | 2012 |
| Abstract | This work demonstrated a successful example of RDRP with CuSO4·5H2O as a Cu(II) based catalyst in the presence of a reducing agent. CuSO4·5H2O produced a more controllable polymerization compared with the widely used CuBr2. The mechanism was revealed to be a Cu(0)-mediated RDRP with the in situ generated Cu(0) from CuSO4·5H2O as the catalyst. This work may provide an alternative, economical and promising copper(II)-based RDRP catalyst, which would eventually enrich and benefit the RDRP technique. |
| Starting Page | 3220 |
| Ending Page | 3223 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2PY20639K |
| Volume Number | 3 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/py/c2/c2py20639k/c2py20639k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2PY20639K |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
