NDLI: Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands

Content Provider	Semantic Scholar
Author	Kapturkiewicz, Andrzej Chen, Teng‐ Ming Laskar, Inamur Rahaman Nowacki, Jacek
Copyright Year	2004
Abstract	Electrogenerated chemiluminescence (ECL) studies have been performed for the iridium(III) cyclometalated L2Ir(acac) complexes with substituted 2-phenylbenzothiazole ligand L. Electron transfer (ET) generation of the excited 3L2Ir(acac) has been studied using a triple-potential-step technique in acetonitrile–dioxane (1:1) solutions containing 0.1 M (n-C4H9)4NPF6 as the supporting electrolyte. ET reactions between electrochemically generated L2Ir(acac)+ and A− (radical anions of aromatic nitriles) species lead to very efficient generation of ECL emission. Extremely high ECL efficiencies (up to 0.40) close to the excited 3L2Ir(acac) luminescence yields have been found.
Starting Page	827
Ending Page	831
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1016/j.elecom.2004.06.006
Alternate Webpage(s)	https://ir.nctu.edu.tw/bitstream/11536/26500/1/000222894600017.pdf
Alternate Webpage(s)	https://doi.org/10.1016/j.elecom.2004.06.006
Volume Number	6
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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