Loading...
Please wait, while we are loading the content...
Similar Documents
Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange
| Content Provider | Semantic Scholar |
|---|---|
| Author | Bury, Wojciech Fairen-Jimenez, David Lalonde, Marianne B. Snurr, Randall Q. Farha, Omar K. Hupp, Joseph T. |
| Copyright Year | 2013 |
| Abstract | Control over catenation in a pillared paddlewheel metal–organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods. |
| Starting Page | 739 |
| Ending Page | 744 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/cm303749m |
| Volume Number | 25 |
| Alternate Webpage(s) | http://chemgroups.northwestern.edu/hupp/Publications/ChemMater-2013-25-739.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/cm303749m |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
