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exo-Methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zecchini, Matteo Lopez, Jordan R. Allen, Scott W. Coles, Simon J. Wilson, Claire V. Akutsu, Hiroki Martin, Lee Wallis, John D. |
| Copyright Year | 2015 |
| Abstract | Hydroxymethyl-BEDT-TTF is converted by tosylation and elimination into exo-methylene-BEDT-TTF whose exocyclic double bond leads to a small increase in the oxidation potential, and from which radical cation salts with perchlorate and triiodide have been prepared, the latter showing semiconductor properties. Allyloxymethyl- and allylthiomethyl-BEDT-TTF, the first BEDT-TTF derivatives with an alkene in the side chain, have been prepared, along with a 1 : 2 radical cation perchlorate salt of the former, an insulator which contains a donor dication. |
| Starting Page | 31104 |
| Ending Page | 31112 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5RA03921E |
| Volume Number | 5 |
| Alternate Webpage(s) | http://irep.ntu.ac.uk/id/eprint/25416/1/EP25416_Wallis.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5RA03921E |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
