Rubidium tetrafluoridobromate(III): redetermination of the crystal structure from single-crystal X-ray diffraction data

Content Provider	Semantic Scholar
Author	Malin, Artem V. Ivlev, Sergei I. Ostvald, Roman Kraus, Florian
Copyright Year	2019
Abstract	Single crystals of rubidium tetrafluoridobromate(III), RbBrF4, were grown by melting and recrystallizing RbBrF4 from its melt. This is the first determination of the crystal structure of RbBrF4 using single-crystal X-ray diffraction data. We confirmed that the structure contains square-planar [BrF4] anions and rubidium cations that are coordinated by F atoms in a square-antiprismatic manner. The compound crystallizes in the KBrF4 structure type. Atomic coordinates and bond lengths and angles were determined with higher precision than in a previous report based on powder X-ray diffraction data [Ivlev et al. (2015). Z. Anorg. Allg. Chem. 641, 2593–2598].
File Format	PDF HTM / HTML
DOI	10.1107/s2414314619015955
Volume Number	4
Alternate Webpage(s)	http://iucrdata.iucr.org/x/issues/2019/11/00/wm4118/wm4118.pdf
Alternate Webpage(s)	https://doi.org/10.1107/s2414314619015955
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article