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Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Turba, Sabrina Walter, Olaf Schindler, Siegfried Nielsen, Lars Preuss Hazell, Alan McKenzie, Christine J. Lloret, Francesc Cano, Joan Julve, Miguel |
| Copyright Year | 2008 |
| Abstract | Copper(II) complexes of the ligand 1,n-bis[bis(2-pyridylmethyl)amino]benzene with n = 2-4 (1,n-tpbd) and its mononuclear derivative bis(2-pyridylmethyl)aniline (phbpa) were synthesized and structurally characterized. Magnetic measurements and DFT calculations were performed on [CuCl2(phbpa)], [Cu2Cl4(1,3-tpbd)], [(Cu2Cl2(ClO4)(1,3-tpbd))Cl(Cu2Cl2(OH2)(1,3-tpbd))](ClO4)2, and [Cu2(OH2)2(S2O6)(1,3-tpbd)]S2O6, and the exchange-polarization mechanism was successfully demonstrated. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ic800244g |
| PubMed reference number | 18798612 |
| Journal | Medline |
| Volume Number | 47 |
| Issue Number | 20 |
| Alternate Webpage(s) | http://geb.uni-giessen.de/geb/volltexte/2008/5506/pdf/TurbaSabrina-2008-02-29.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ic800244g |
| Journal | Inorganic chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |