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Oxidative “reverse-esterification” of ethanol with benzyl/alkyl alcohols or aldehydes catalyzed by supported rhodium nanoparticles
| Content Provider | Semantic Scholar |
|---|---|
| Author | Guha, Nitul Ranjan Sharma, Saurabh Bhattacherjee, Dhananjay Thakur, Vandna Bharti, Richa Reddy, Chennayala Bal Das, Pralay |
| Copyright Year | 2016 |
| Abstract | A very unusual role of polystyrene stabilized rhodium (Rh@PS) nanoparticles as a supported catalyst is described for “reverse-esterification” of ethanol with benzyl/alkyl alcohols or aldehydes. Faster and selective oxidation of ethanol to acetaldehyde and H2 under Rh@PS catalyzed conditions which restricted further oxidation of benzyl/alkyl alcohols and their in situ reaction gave the corresponding acetate esters following the dehydrogenative-coupling approach. A hitherto redox dehydrogenative-coupling of ethanol and aldehydes has also been explored for the same acetate ester synthesis under Rh@PS catalyzed conditions. |
| Starting Page | 1206 |
| Ending Page | 1211 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5GC02513C |
| Volume Number | 18 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C5GC02513C |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/gc/c5gc02513c/c5gc02513c1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5GC02513C |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
