NDLI: Spontaneous formation of hexameric resorcinarene capsule in chloroform solution as detected by diffusion NMR.

Content Provider	Semantic Scholar
Author	Avram, Liat Cohen, Yoram
Copyright Year	2002
Abstract	NMR diffusion measurements provide unequivocal proof that the resorcinarene 1b self-assembles spontaneously into a stable hexamer capsule in chloroform solution by encapsulating several chloroform molecules, which occupy different chemical positions. Although the affinity of tetrahexylammonium bromide (2a) toward the cavity of the hexamer is much higher than that of the chloroform molecules, it was found that the same amount of DMSO is needed to disrupt the two hexamers, thus suggesting similar stabilities for these two supramolecular capsules.
File Format	PDF HTM / HTML
DOI	10.1021/ja0272686
PubMed reference number	12487570
Journal	Medline
Volume Number	124
Issue Number	51
Alternate Webpage(s)	http://www.tau.ac.il/~ycoheng/Documents/57.pdf
Alternate Webpage(s)	https://doi.org/10.1021/ja0272686
Journal	Journal of the American Chemical Society
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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