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Synthesis and Crystal Structures of the P,N-Substituted Ferrocenes [Fe{η5-C5H4–P(S)Ph2}(η5-C5H4–NHCH2tBu)] and [Fe(η5-C5H4– PPh2)(η5-C5H4–NHCH2tBu)]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ritte, Michael Bruhn, Clemens Siemeling, Ulrich |
| Copyright Year | 2014 |
| Abstract | The P,N-substituted ferrocene [Fe{η5-C5H4-P(S)Ph2}(η5-C5H4-NHCH2tBu)] was prepared in six steps from the bromo derivative [Fe{η5-C5H4-PPh2}(η5-C5H4-Br)]. Its reductive desulfurisation with Raney nickel afforded the corresponding phosphino-substituted derivative [Fe(η5-C5H4- PPh2)(η5-C5H4-NHCH2tBu)]. Both compounds have been structurally characterised by singlecrystal X-ray diffraction studies. Graphical Abstract Synthesis and Crystal Structures of the P,N-Substituted Ferrocenes [Fe{η5-C5H4–P(S)Ph2}(η5-C5H4–NHCH2tBu)] and [Fe(η5-C5H4– PPh2)(η5-C5H4–NHCH2tBu)] |
| Starting Page | 906 |
| Ending Page | 912 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.5560/znb.2014-4132 |
| Volume Number | 69 |
| Alternate Webpage(s) | http://www.znaturforsch.com/s69b/s69b0906.pdf |
| Alternate Webpage(s) | https://doi.org/10.5560/znb.2014-4132 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |