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Characterization of nitrogen compounds in coker gas oil by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry and Fourier transform infrared spectroscopy
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xiaobo, Chen Yibin, Liu Jin, Wang Honghong, Shan Chaohe, Yang Chunyi, Li |
| Copyright Year | 2014 |
| Abstract | In this study, the classes and structures of nitrogen species in coker gas oil (CGO) are characterized by electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) combined with Fourier transform infrared (FT-IR) spectroscopy. The results demonstrate that the m/z of basic and non-basic nitrogen compounds ranges from 180 to 560 and from 200 to 460, respectively. Six basic nitrogen compounds, N1 (a molecule contains one nitrogen atom, similarly hereinafter), N1O1, N1O1S1, N1O2, N1S1, and N2, are identified by their positive-ion mass spectra, and four non-basic nitrogen compounds, N1, N1O1, N1S1, and N2, are characterized by their negative-ion mass spectra. Among these nitrogen compounds, the N1 class species are the most predominant. Combined with the data of ESI FT-ICR MS and FT-IR, the basic N1 class species are likely pyridines, naphthenic pyridines, quinolines, and benzoquinolines. The most non-basic N1 class species are derivatives of benzocarbazole. The N2 class species are likely amphoteric molecules with pyridine and pyrrole core structures. |
| Starting Page | 417 |
| Ending Page | 422 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 27656342v1 |
| Volume Number | 4 |
| Journal | Applied petrochemical research |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Class Cyclotrons Gases Ions Mice, Inbred ICR Nitrogen Compounds, Inorganic Pyridines Pyrroles Quinolines Spectrometry Spectrometry, Mass, Electrospray Ionization X-Ray Emission Spectroscopy lead naphthenate |
| Content Type | Text |
| Resource Type | Article |