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Kinetics of reduction of hydroxycuprate(III) in KOH solution
| Content Provider | Semantic Scholar |
|---|---|
| Author | Misevičius, Algirdas Rozovskis, Grigorijus |
| Copyright Year | 2002 |
| Abstract | The solution of an unstable copper(III) complex, hydroxycuprate(III) i.e. Cu(OH)−4, has been obtained by oxidising a copper anode in 0.5–3 M KOH solution. The kinetics of the copper(III) reduction in KOH solution has been studied spectrophotometrically and is first order with respect to copper(III), and the pseudo-first order rate constant increases as the KOH concentration increases. The kinetic data is explained by a scheme according to which a CuIII intermediate, in equilibrium with Cu(OH)−4, reacts with OH−. On the basis of the kinetic data, the molar absorptivity of the Cu(OH)−4 solution has been determined. |
| Starting Page | 99 |
| Ending Page | 101 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1023/A:1013465320009 |
| Volume Number | 27 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1023/A:1013465320009 |
| Alternate Webpage(s) | https://doi.org/10.1023/A%3A1013465320009 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
