Determination of the theoretical rate constants for the reduction reactions of lanthanide ions by hydrated electrons

Content Provider	Semantic Scholar
Author	Lee, Kwang-Pill Park, Keung-Shik Kang, Duck-Won Yamada, Yasuhiro Ohno, Shin-Ichi
Copyright Year	1998
Abstract	The mechanism of the reduction reaction of lanthanide(III) ions by hydrated electrons in polar solvents has been investigated. The theoretical rate constants for the reaction of hydrated electrons with a number of lanthanide ions have been calculated using the energy gap laws of the charge shift reaction(D+−A→D−A+) and compared with experimental values. With these results, we have explained the large difference of the reaction rates of lanthanide ions with hydrated electrons, which depend upon the kind of lanthanide ion. The calculated results agree almost quantitatively with the experimental values.
Starting Page	17
Ending Page	20
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1007/BF02385930
Volume Number	235
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1007/BF02385930
Alternate Webpage(s)	https://doi.org/10.1007/BF02385930
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article