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One-pot Alkene Hydroboration/migratory Suzuki-miyaura Cross-coupling
| Content Provider | Semantic Scholar |
|---|---|
| Author | Baumgartner, Yann Kato, Daiki Cavalli, Diana Baudoin, Olivier |
| Copyright Year | 2019 |
| Abstract | The development of C-H bond functionalization has exponentially increased since the start of the 21th century expanding the organic reaction toolbox. Challenging siteselective transformations were e.g. achieved with the introduction of a directing group or by exploiting the intrinsic reactivity of the substrates. An alternative to these extensively researched methods exploits the controlled migration of the organotransition-metal species along an alkyl chain to the cross-coupling site. Our group has been employing this strategy multiple times over the last years for the Pdcatalyzed βor longer-range arylation of ester enolates, secondary organozinc reagents as well as surrogates. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://esoc2019.abstracts.eu/dkFCQzlpdUJoT3BUMEQ3YWRPZ2sybC93STdqdUV6emdUbFRSV0N1d3JVND0=.pdf |
| Alternate Webpage(s) | https://esoc2019.abstracts.eu/50b73bffbc0b99e99627b646ed8bb234.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
