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Network structures with 2,2′-bipyridine-3,3′diol: a discrete Co(III) complex that forms a porous 3-D hydrogen bonded network, and Cu(II) coordination chains
| Content Provider | Semantic Scholar |
|---|---|
| Author | Stephenson, Maria D. Hardie, Michaele J. |
| Copyright Year | 2007 |
| Abstract | The complex [Co(bpydiol-H)3]·H2O, where bpydiol is 2,2′-bipyridine-3,3′-diol, features a simple octahedral tris-chelate complex that forms a honeycomb-like six-connected 3-D network of 4966 topology through weak C–H⋯O hydrogen bonding. The network shows significant channels and the material is remarkably robust. The water guest molecules can be solvent exchanged for 1,2-dibromobenzene molecules. Cu(II) complexes of bpydiol are also reported: [Cu(bpydiol-H)X], where X = Cl−, Br−, or NO3−, which all have coordination chain structures. The coordination chains in [Cu(bpydiol-H)(NO3)] assemble through weak CH.ONO2 hydrogen bonds to form a corrugated 2-D network. |
| Starting Page | 496 |
| Ending Page | 502 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B702509M |
| Volume Number | 9 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/CE/b7/b702509m/b702509m.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
