NDLI: Cobalt catalyzed sp3 C–H amination utilizing aryl azides† †Electronic supplementary information (ESI) available. CCDC 1057198–1057200. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01162k

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Cobalt catalyzed sp3 C–H amination utilizing aryl azides† †Electronic supplementary information (ESI) available. CCDC 1057198–1057200. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01162k

Content Provider	Semantic Scholar
Author	Villanueva, Omar Everleny Pérez Weldy, Nina Mace Blakey, Simon B. Beth, Cora E. Mac
Copyright Year	2015
Abstract	A dinuclear Co(ii) complex supported by a modular, tunable redox-active ligand system is capable of selective C-H amination to form indolines from aryl azides in good yields at low (1 mol%) catalyst loading. The reaction is tolerant of medicinally relevant heterocycles, such as pyridine and indole, and can be used to form 5-, 6-, and 7-membered rings. The synthetic versatility obtained using low loadings of an earth abundant transition metal complex represents a significant advance in catalytic C-H amination technology.
Starting Page	6672
Ending Page	6675
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/c5sc01162k
PubMed reference number	29435216
Journal	Medline
Volume Number	6
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01162K
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/sc/c5sc01162k/c5sc01162k1.pdf
Alternate Webpage(s)	http://pubs.rsc.org/en/content/getauthorversionpdf/C5SC01162K
Alternate Webpage(s)	https://open.library.emory.edu/publications/emory:s8805/pdf/
Alternate Webpage(s)	https://doi.org/10.1039/c5sc01162k
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Cobalt catalyzed sp3 C–H amination utilizing aryl azides† †Electronic supplementary information (ESI) available. CCDC 1057198–1057200. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01162k

A redox-active diborane platform performs C(sp3)–H activation and nucleophilic substitution reactions† †Electronic supplementary information (ESI) available. CCDC 1819687–1819695. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc00743h

A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids† †Electronic supplementary information (ESI) available. CCDC 1877103. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00603f

Nickel-catalyzed oxidative C–H/N–H annulation of N-heteroaromatic compounds with alkynes† †Electronic supplementary information (ESI) available. CCDC 1868340. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05063e

Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides† †Electronic supplementary information (ESI) available. CCDC 1436785. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc00082g

Copper-catalyzed enantioselective arylalkynylation of alkenes† †Electronic supplementary information (ESI) available. CCDC 1908198. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc04029c

Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids† †Electronic supplementary information (ESI) available. CCDC 1838875. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc02101e

Site-selective C–H activation and regiospecific annulation using propargylic carbonates† †Electronic supplementary information (ESI) available. CCDC 1866187. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc01703h

Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution† †Electronic supplementary information (ESI) available. CCDC 1868011. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05143g

Cobalt catalyzed sp3 C–H amination utilizing aryl azides† †Electronic supplementary information (ESI) available. CCDC 1057198–1057200. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01162k

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